Answer:
2Ag⁺ (aq) + CrO₄⁻² (aq) ⇄ Ag₂CrO₄ (s) ↓
Ksp = [2s]² . [s] → 4s³
Explanation:
Ag₂CrO₄ → 2Ag⁺ + CrO₄⁻²
Chromate silver is a ionic salt that can be dissociated. When we have a mixture of both ions, we can produce the salt which is a precipitated.
2Ag⁺ (aq) + CrO₄⁻² (aq) ⇄ Ag₂CrO₄ (s) ↓ Ksp
That's the expression for the precipitation equilibrium.
To determine the solubility product expression, we work with the Ksp
Ag₂CrO₄ (s) ⇄ 2Ag⁺ (aq) + CrO₄⁻² (aq) Ksp
2 s s
Look the stoichiometry is 1:2, between the salt and the silver.
Ksp = [2s]² . [s] → 4s³
Answer:
1. EF = PSCl₃; 2. MF = PSCl₃
Explanation:
1. Empirical formula
The empirical formula is the simplest whole-number ratio of atoms in a compound.
The ratio of atoms is the same as the ratio of moles.
So, our first job is to calculate the molar ratio of P:S:Cl.
Assume 100 g of the compound.
(a) Calculate the mass of each element.
Then we have 18.28 g P, 18.93 g S, and 67.28 g Cl.
(b) Calculate the moles of each element
(c) Calculate the molar ratio of the elements
Divide each number by the smallest number of moles
P:S:Cl = 0.5902:0.5905:1.898 = 1:1.000:3.000 ≈ 1:1:3
(d) Write the empirical formula
EF = PSCl₃
The empirical formula for this compound is PSCl₃.
2. Molecular formula
(a) Calculate the ratio of the molecular and empirical formula masses
n = (169.4 u)/(169.40 u) = 1.000 ≈ 1
(b) Calculate the molecular formula
MF = (EF)ₙ = (EF)₁ = PSCl₃
The molecular formula for this compound is PSCl₃.
The empirical formula of the compound is PSCl₃.
To find the empirical formula, we first need to find the moles of each element in the compound. We can do this by dividing the mass of each element by its molar mass. The molar masses of the elements are:
P = 30.97 g/mol
S = 32.06 g/mol
Cl = 35.45 g/mol
The mass percentages given are for 100 g of the compound. So, the mass of each element in 100 g of the compound is:
P = 18.28 g
S = 18.93 g
Cl = 62.78 g
The moles of each element are then:
P = 18.28 g / 30.97 g/mol = 0.590 mol
S = 18.93 g / 32.06 g/mol = 0.590 mol
Cl = 62.78 g / 35.45 g/mol = 1.770 mol
The smallest whole number ratio of the moles of each element is 1:1:3. So, the empirical formula of the compound is PSCl3.
The molecular formula of the compound can be the same as the empirical formula, or it can be a multiple of the empirical formula. The molecular formula is not given, so we cannot say for sure what it is. However, we can say that the molecular formula must be a whole number multiple of the empirical formula PSCl3.
Learn more about empirical formula,here:
#SPJ3
Answer:
Ea =22542.6
Explanation:
The rate constant k is affected by the temperature and this dependence may be represented by the Arrhenius equation:
where the pre-exponential factor A is assumed to be independent of temperature, R is the gas constant, and T the temperature in K. Taking the natural logarithm of this equation gives:
ln k = ln A - Ea/(RT)
or
ln k = -Ea/(RT) + constant
or
ln k = -(Ea/R)(1/T) + constant
These equations indicate that the plot of ln k vs. 1/T is a straight line, with a slope of -Ea/R. These equations provide the basis for the experimental determination of Ea.
now applying the above equation in the problem
we can write that
solve for Ea:
Ea = R[Ln(k2/k1)] / [(1/T1) - (1/T2)]
but k_2 = 2 k_1, hence:
Ea = (8.314 J/moleK)[ln(2)] / [(1/273+45) - (1/273+73)]
Ea =22542.6
Answer:
The activation energy for this reaction is 22.6 kJ/ mol
Explanation:
Step 1: Data given
Rate constant doubles when Temperature goes from 45.0 °C to 73.0 °C
R = 8.314 J/K*mol
Step 2: Calculate the activation energy
Log (k2/k1) = Ea / 2.303R *((1/T1) - (1/T2))
⇒ with k1 = initial rate constant
⇒ with k2 = rate constant after doubled = 2k1
⇒ T1 = initial temperature = 45.0 °C = 318 Kelvin
⇒ T2 = Final temperature = 73.0 °C = 346 Kelvin
log (2) = Ea / (2.303*8.314) *((1/318) - (1/346))
log(2) = Ea / (2.303*8.314) * 0.00025448
Ea = 22649 J/mol = 22.6 kJ/mol
The activation energy for this reaction is 22.6 kJ/ mol
Answer:
Ca₃(AsO₃)₂
Explanation:
Sodium arsenite, with the chemical formula Na₃AsO₃, is formed by the cation Na⁺ and the anion AsO₃³⁻. For the molecule to be neutral, 3 cations Na⁺ and 1 anion AsO₃³⁻ are required.
Calcium arsenite would be formed by the cation Ca²⁺ and the anion AsO₃³⁻. For the molecule to be neutral, we require 3 cations Ca²⁺ and 2 anions AsO₃³⁻. The resulting chemical formula is Ca₃(AsO₃)₂.
#edge2021
Answer:
it's b.
Explanation:
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Answer:
Multiply the subscripts of the empirical formula by the value of the ratio of the molar mass of the compound to the empirical molar mass of the compound.
Explanation:
got it right on edge 2020 :)
Answer:
Multiply the subscripts of the empirical formula by the value of the ratio of the molar mass of the compound to the empirical molar mass of the compound.
Explanation:
Answer : The rate for the formation of hydrogen is, 1.05 M/s
Explanation :
The general rate of reaction is,
Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.
The expression for rate of reaction will be :
From this we conclude that,
In the rate of reaction, A and B are the reactants and C and D are the products.
a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.
The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.
The given rate of reaction is,
The expression for rate of reaction :
The rate of reaction expression is:
As we are given that:
Now we to determine the rate for the formation of hydrogen.
Thus, the rate for the formation of hydrogen is, 1.05 M/s