Answer: 1.5 M
Explanation:
Answer:
pH = 11.7
Explanation:
pOH= -log [OH]=-log[0.05]
=2.3
pOH+pH= 14
pH= 14-2.3= 11.7
Answer:
The free energy = -20.46 KJ
Explanation:
given Data:
Pb²⁺ = 0.750 M
Br⁻ = 0.232 M
R = 8.314 Jk⁻¹mol⁻¹
T = 298K
The Gibb's free energy is calculated using the formula;
ΔG = ΔG° + RTlnQ -------------------------1
Where;
ΔG° = standard Gibb's freeenergy
R = Gas constant
Q = reaction quotient
T = temperature
The chemical reaction is given as;
Pb²⁺(aq) + 2Br⁻(aq) ⇄PbBr₂(s)
The ΔG°f are given as:
ΔG°f (PbBr₂) = -260.75 kj.mol⁻¹
ΔG°f (Pb²⁺) = -24.4 kj.mol⁻¹
ΔG°f (2Br⁻) = -103.97 kj.mol⁻¹
Calculating the standard gibb's free energy using the formula;
ΔG° = ξnpΔG°(product) - ξnrΔG°(reactant)
Substituting, we have;
ΔG° =[1mol*ΔG°f (PbBr₂)] - [1 mol *ΔG°f (Pb²⁺) +2mol *ΔG°f (2Br⁻)]
ΔG° =(1 *-260.75 kj.mol⁻¹) - (1* -24.4 kj.mol⁻¹) +(2*-103.97 kj.mol⁻¹)
= -260.75 + 232.34
= -28.41 kj
Calculating the reaction quotient Q using the formula;
Q = 1/[Pb²⁺ *(Br⁻)²]
= 1/(0.750 * 0.232²)
= 24.77
Substituting all the calculated values into equation 1, we have
ΔG = ΔG° + RTlnQ
ΔG = -28.41 + (8.414*10⁻³ * 298 * In 24.77)
= -28.41 +7.95
= -20. 46 kJ
Therefore, the free energy of reaction = -20.46 kJ
To calculate the reaction free energy ΔG for this reaction, we need to use the standard free energy of formation values given in a data tab, the stoichiometry of the reaction, and the specific conditions of the reaction, including the concentrations of Pb2+ and Br−. After a series of calculations, we will get the ΔG value in joules, which can be converted to kilojoules.
The task here is to calculate the reaction free energy ΔG for the Pb2+(aq) + 2Br−(aq) = PbBr2(s) reaction at 25.0°C. From the given information, we can start by calculating the number of moles of PbBr2 from its mass. Then, referring to the thermodynamic data tab of the ALEKS, we find the standard free energy of formation (ΔGf°) values for Pb2+(aq), Br−(aq), and PbBr2(s). Now, we can use these values and the definition of ΔG for a reaction in terms of ΔGf° values and stoichiometry.
ΔG = ΣΔGf°(products) - ΣΔGf°(reactants).
Note that the equation must be balanced so each ΔGf° value is multiplied by the stoichiometric coefficient of that substance in the reaction. It is also important to remember to convert the answer to kilojoules if the ΔGf° values are given in joules/mole. Lastly, the concentrations of Pb2+ and Br− are included in the reaction quotient Q to show the reaction's non-standard conditions.
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Answer:
Br - C ≡ N
Explanation:
To draw the Lewis line-bond structure we need to bear in mind the octet rule, which states that in order to gain stability each atom tends to share electrons until it has 8 electrons in its valence shell.
The most stable structure that respects these premises is:
Br - C ≡ N
It does not have any H atom.
B. 0.288 g
C. 0.392 g
D. 0.450 g
E. 0.341 g
Answer: The correct option is E.
Explanation: The reaction between aspirin (also known as acetylsalicylic acid) and sodium hydroxide is known as acid-base titration reaction.
By applying Unitary method, we get:
15.50mL of NaOH dissolves = 0.325 g of aspirin
So, 16.25 mL of NaOH will dissolve = = 0.341 g
Hence, the correct option is E.
b. 8.5 x 10-6 M
c. 6.3 x 10-11 M
d. 1.3 x 10-12 M
e. 5.0 x 10-2 M
f. 1.8 x 10-5 M
Answer:
c. 6,3x10⁻¹¹M
Explanation:
The solubility of a buffer is defined as the concentration of the dissolved solid in a saturated solution. For the Cd(OH)₂, solubility is:
[Cd²⁺] = S
The dissolution of Cd(OH)₂ is:
Cd(OH)₂ ⇄ Cd²⁺ + 2OH⁻
And the ksp is defined as:
ksp = [Cd²⁺][OH⁻]²
As ksp = 2,5x10⁻¹⁴ and [OH⁻] at pH=12,30 = 10^-(14-12,30) = 0,01995M
2,5x10⁻¹⁴ = [Cd²⁺]×(0,01995M)²
[Cd²⁺] = 6,3x10⁻¹¹M
That means solubility is c. 6,3x10⁻¹¹M
I hope it helps!
The molar solubility of Cd(OH)2 when buffered at a pH of 12.30 can be calculated using the concept of hydrolysis. The correct answer is 6.3 x 10^(-11) M.
To calculate the molar solubility of Cd(OH)2 when buffered at a pH of 12.30, we need to use the concept of hydrolysis. Cd(OH)2 is a slightly soluble salt that undergoes hydrolysis in aqueous solution. At a high pH value, OH- ions react with water to form more OH- ions, shifting the equilibrium towards the hydrolysis reaction.
After performing the calculations, the molar solubility of Cd(OH)2 when buffered at a pH of 12.30 is approximately 6.3 x 10^(-11) M. Therefore, the correct answer is option c. 6.3 x 10^(-11) M.
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Answer:
a) The wavelength of the baseball is .
b) 9.131 nm is the wavelength of a hydrogen atom at the 43.35 m/s.
Explanation:
Velocity of the baseball = v = 97 mile/hour
1 mile = 1609 meter
1 hour = 3600 seconds
Mass of baseball = m = 0.148 kg
Wavelength of the baseball:
De Broglie wavelength
h =Planck's constant
The wavelength of the baseball is .
b)
Mass of the hydrogen atom =
Velocity of hydrogen atom = u = 43.35 m/s
De Broglie wavelength
9.131 nm is the wavelength of a hydrogen atom at the 43.35 m/s.
To calculate the wavelength of the baseball and hydrogen atom, we can use the wavelength formula. However, the wavelengths calculated are extremely small and cannot be practically detected.
To calculate the wavelength of the baseball, we can use the wavelength formula: λ = v/f. In this case, the velocity (v) of the baseball is given as 97 mph, which is equal to 97 * 1609 m/h. The frequency (f) can be calculated by dividing the speed of light (3 * 10^8 m/s) by the wavelength of the baseball.
For the hydrogen atom, we can use the same formula. However, we need to convert the hydrogen atom velocity to m/s. Once we have the velocity in m/s, we can calculate the wavelength by dividing the velocity by the frequency.
It is important to note that the wavelength calculated for the baseball and hydrogen atom are extremely small and cannot be practically detected by our senses or instruments.
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