Answer:
Explanation:
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In this case, since the determination of an empirical formula is covered by first computing the moles of each atom as shown below:
Now, we divide each moles by the fewest moles (those of oxygen), to obtain the subscripts in the empirical formula:
Thus, the empirical formula, taken to the nearest whole subscript is:
Whose molar mass is 180.16, therefore the empirical formula is the same to the molecular one.
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According to the molecular geometry, there are two lone pairs on central atom of BrF₃.
Molecular geometry can be defined as a three -dimensional arrangement of atoms which constitute the molecule.It includes parameters like bond length,bond angle and torsional angles.
It influences many properties of molecules like reactivity,polarity color,magnetism .The molecular geometry can be determined by various spectroscopic methods and diffraction methods , some of which are infrared,microwave and Raman spectroscopy.
They provide information about geometry by taking into considerations the vibrational and rotational absorbance of a substance.Neutron and electron diffraction techniques provide information about the distance between nuclei and electron density.
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Answer:
BrF3 has 2 lone pairs (4 unshared electrons)
Explanation:
Answer:
Mass PbI2 = 18.19 grams
Explanation:
Step 1: Data given
Volume solution = 99.8 mL = 0.0998 L
mass % KI = 12.0 %
Density = 1.093 g/mL
Volume of the other solution = 96.7 mL = 0.967 L
mass % of Pb(NO3)2 = 14.0 %
Density = 1.134 g/mL
Step 2: The balanced equation
Pb(NO3)2(aq) + 2 KI(aq) ⇆ PbI2(s) + 2 KNO3(aq)
Step 3: Calculate mass
Mass = density * volume
Mass KI solution = 1.093 g/mL * 99.8 mL
Mass KI solution = 109.08 grams
Mass KI solution = 109.08 grams *0.12 = 13.09 grams
Mass of Pb(NO3)2 solution = 1.134 g/mL * 96.7 mL
Mass of Pb(NO3)2 solution = 109.66 grams
Mass of Pb(NO3)2 solution = 109.66 grams * 0.14 = 15.35 grams
Step 4: Calculate moles
Moles = mass / molar mass
Moles KI = 13.09 grams / 166.0 g/mol
Moles KI = 0.0789 moles
Moles Pb(NO3)2 = 15.35 grams / 331.2 g/mol
Moles Pb(NO3)2 = 0.0463 moles
Step 5: Calculate the limiting reactant
For 1 mol Pb(NO3)2 we need 2 moles KI to produce 1 mol PbI2 and 2 moles KNO3
Ki is the limiting reactant. It will completely be consumed ( 0.0789 moles). Pb(NO3)2 is in excess. There will react 0.0789/2 = 0.03945 moles. There will remain 0.0463 - 0.03945 = 0.00685 moles
Step 6: Calculate moles PbI2
For 1 mol Pb(NO3)2 we need 2 moles KI to produce 1 mol PbI2 and 2 moles KNO3
For 0.0789 moles KI we'll have 0.0789/2 = 0.03945 moles PbI2
Step 7: Calculate mass of PbI2
Mass PbI2 = moles PbI2 * molar mass PbI2
Mass PbI2 = 0.03945 moles * 461.01 g/mol
Mass PbI2 = 18.19 grams
Answer:
Explanation:
Hello,
In this case, we write the reaction again:
In such a way, the first thing we do is to compute the reacting moles of lead (II) nitrate and potassium iodide, by using the concentration, volumes, densities and molar masses, 331.2 g/mol and 166.0 g/mol respectively:
Next, as lead (II) nitrate and potassium iodide are in a 1:2 molar ratio, 0.04635 mol of lead (II) nitrate will completely react with the following moles of potassium nitrate:
But we only have 0.07885 moles, for that reason KI is the limiting reactant, so we compute the yielded grams of lead (II) iodide, whose molar mass is 461.01 g/mol, by using their 2:1 molar ratio:
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Answer:
The strength of a bond depends on the amount of overlap between the two orbitals of the bonding atoms
Orbitals bond in the directions in which they protrude or point to obtain maximum overlap
Explanation:
The valence bond theory was proposed by Linus Pauling. Compounds are firmed by overlap of atomic orbitals to attain a favourable overlap integral. The better the overlap integral (extent of overlap) the better or stringer the covalent bond.
Orbitals overlap in directions which ensure a maximum overlap of atomic orbitals in the covalent bond.
Answer:
THE STRENGTH OF THE BOND DEPENDS ON THE AMOUNT OF OVERLAP BETWEEN THE TWO ORBITALS OF THE BONDING ATOMS
ORBITALS BOND IN THE DIRECTION OR POINT IN WHICH THEY PROTRUDE OR POINT TO OBTAIN MAXIMUM OVERLAP.
Explanation:
Valence bond theory describes the covalent bond as the overlap of half-filled atomic orbital yields a pair of electrons shared between the two bonded atoms. Overlapping of orbitals occurs when a portion of one orbital and the other occur in the same region of space. The strength of a bond is determined by the amount of overlap between the two orbitals of the bonding atoms. In other words, orbitals that overlap more and in the right orientation of maximum overlapping form stronger bonds that those with less overlap and right orientation for maximum overlap. The bonding occurs at a varying distance in different atoms from which it obtains its stable energy caused by the increase in the attraction of nuclei for the electrons.
Orbitals also bond in the direction to obtain maximum overlap as orientation of the atoms also affect overlap. The greater overlap occurs when atoms are oriented on a direct line mostly end to end or side by side between the two nuclei depending on the type of bond formed. A sigma bond is formed when atoms overlap end to end in which a straight line exists between the two atoms that is the internuclear axis indicating the concentrated energy density in that region. Pi bond exits in when overlap occurs in the side -to -side orientation and the energy density is concentrated opposite the internuclear axis.
Answer : The pH of the solution is, 5.24
Explanation :
First we have to calculate the volume of
Formula used :
where,
are the initial molarity and volume of .
are the final molarity and volume of .
We are given:
Putting values in above equation, we get:
Now we have to calculate the total volume of solution.
Total volume of solution = Volume of + Volume of
Total volume of solution = 160.0 mL + 1086.79 mL
Total volume of solution = 1246.79 mL
Now we have to calculate the Concentration of salt.
Now we have to calculate the pH of the solution.
At equivalence point,
Thus, the pH of the solution is, 5.24
Answer:
THE NEW FREEZING POINT IS -4.196 °C
Explanation:
ΔTf = 1 Kf m
molarity of MgCl2:
Molar mass = (24 + 35.5 *2) g/mol
molar mass = 95 g/mol
7.15 g of MgCl2 in 100 g of water
7.15 g = 100 g
(7.15 * 100 / 1000) = 1000 g or 1 L or 1 dm3
= 0.715 g /dm3
Molarity in mol/dm3 = molarity in g/dm3 / molar mass
= 0.715 g /dm3 / 95 g/mol
m = 0.00752 mol/ dm3
So therefore:
ΔTf = i Kf m
1 = 3 (1 Mg and 2 Cl)
Kf = 1.86 °C/m
M = 0.752 moles
So we have:
ΔTf = 3 * 1.86 * 0.752
ΔTf = 4.196 °C
The new freezing point therefore will be 0 °C - 4.196 °C which is equals to - 4.196 °C
Answer:
(a)
Explanation:
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In this case, such nomenclature expresses the amount of both phosphorous and chlorine atoms via prefixes for the sub indexes of each atom into the molecule, thus, as phosphorous is prefixless one infers that there is just one phosphorous and five chlorides since the prefix for such atom is penta. Therefore, the correct formula is:
Hence, the answer is (a)
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Answer:
The correct formula for phosphorus pentachloride is a) PCl5