Answer:
2 litres of pure alcohol will be added to make the overall concentration of 9 litres of mixture as 30%.
Explanation:
Suppose x is the number of litres added to the 10% mixture than the quantity of new mixture is given as below
Also the quantity of alcohol is given as
Now the equation is as
So 2 litres of pure alcohol will be added to make the overall concentration of 9 litres of mixture as 30%.
The chemist uses 11 g of CaF2 and an excess of H2SO4, and the reaction produces 2.2 g of HF.
(a) Calculate the theoretical yield of HF.
(b) Calculate the percent yield of HF.
Answer:
39.3%
Explanation:
CaF2 + H2SO4 --> CaSO4 + 2HF
We must first determine the limiting reactant, the limiting reactant is the reactant that yields the least number of moles of products. The question explicitly says that H2SO4 is in excess so CaF2 is the limiting reactant hence:
For CaF2;
Number of moles reacted= mass/molar mass
Molar mass of CaF2= 78.07 g/mol
Number of moles reacted= 11g/78.07 g/mol = 0.14 moles of Calcium flouride
Since 1 mole of calcium fluoride yields two moles of 2 moles hydrogen fluoride
0.14 moles of calcium fluoride will yield 0.14×2= 0.28 moles of hydrogen fluoride
Mass of hydrogen fluoride formed (theoretical yield) = number of moles× molar mass
Molar mass of hydrogen fluoride= 20.01 g/mol
Mass of HF= 0.28 moles × 20.01 g/mol= 5.6 g ( theoretical yield of HF)
Actual yield of HF was given in the question as 2.2g
% yield of HF= actual yield/ theoretical yield ×100
%yield of HF= 2.2/5.6 ×100
% yield of HF= 39.3%
b. 0.03954 g to 0.040 g
c. 20.0332 g to 20,0 g
d. 04.05438 g to 4,054 g
e. 103.692 g to 103.7g
Answer:
c. 20.0332 g to 20,0 g
Explanation:
A significant figure is each of the digits of a number that are used to express it to the required degree of accuracy, starting from the first non-zero digit, with the exception of the trailing zeros.
Which of the following examples illustrates a number that is correctly rounded to three significant figures?
a. 109 526 g to 109 500 g. NO. The rounded number has 4 significant figures: 109 500.
b. 0.03954 g to 0.040 g. NO. The rounded number has 2 significant figures: 0.040.
c. 20.0332 g to 20.0 g. YES. The rounded number has 3 significant figures: 20.0.
d. 04.05438 g to 4.054 g. NO. The rounded number has 4 significant figures: 4.054.
e. 103.692 g to 103.7g. NO. The rounded number has 4 significant figures: 103.7.
Answer: [H3O+]= 0.05 M
Explanation:
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Answer:
an element is a atom like titanium and a compound is like a water, glucose, alcohol and salt
Explanation:
the titanium is a element and water, glucose, alcohol, and salt those are a compound
An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:
Ni(s)VO2+(aq,0.083M)+2H+(aq,1.1M)+e−→→Ni2+(aq,2.5M)+2e−VO2+(aq,2.5M)+H2O(l)
Calculate the cell potential under these nonstandard concentrations.
Express the cell potential to two decimal places and include the appropriate units.
Answer:
Cell potential under non standard concentration is 4.09 v
Explanation:
To solve this problem we need to use Nernst Equation because concentrations of the components of the chemical reactions are differents to 1 M (normal conditions: 1 M , 1 atm).
Nernst equation at 25ºC is:
where
E: Cell potential (non standard conditions)
= Cell potential (standard conditions)
n: Number of electrons transfered in the redox reaction
Q: Reaction coefficient (we are going to get it from the balanced chemical reaction)
For example, consider the following general chemical reaction:
aA + bB --> cC + dD
where
a, b, c, d: coefficient of balanced chemical reaction
A,B,C,D: chemical compounds in the reaction.
Using the previous general reaction, expression of Q is:
Previous information is basic to solve this problem. Let´s see the Nernst equation, we need to know: , n and Q
Let´s calcule potential in nomal conditions ():
1. We need to know half-reactions (oxidation and reduction), we take them from the chemical reaction given in this exercise:
Half-reactions: Eo (v):
+ e- --> -0.23
+ 2 e- +0.99
Balancing each half-reaction, first we are going to balance mass and then we will balance charge in each half-reaction and then charge between half-reactions:
Half-reactions: Eo (v):
2 * [ + e- --> ] -0.23
1 * [ + 2 e- ] +0.99
------------------------------------------------------------------- -------------
2 + 2e- + Ni --> 2 + + 2e- 0.76 v
Then global balanced chemical reaction is:
2 + Ni --> 2 +
and the potential in nomal conditions is:
= 0.76 v
Also from the balanced reaction, we got number of electons transfered:
n = 2
2. Calculate Q:
Now using previous information, we can establish Q expression and we can calculate its value:
From the exercise we know:
3. Use Nernst equation:
Finally, we replace all these results in the Nernst equation:
Cell potential under non standard concentration is 4.09 v
To calculate the cell potential under nonstandard conditions, we need to apply the Nernst Equation. This involves finding the reaction quotient (Q) from the given concentrations and then subtracting a value derived from Q and the number of electrons transferred, from the cell potential under standard conditions.
For calculating the cell potential under nonstandard conditions for an electrochemical cell, we need to use the Nernst equation. In this case, the Nernst Equation is Ecell = E∘cell - (0.0592/n) * logQ, where Q, the reaction quotient, is the ratio of the concentrations of the products to the reactants raised to their stoichiometric coefficients.
Given the half-cell reduction potentials, we can calculate the cell potential under standard conditions (E°cell) by subtracting the potential of the anode from the potential of the cathode (E°cell = Ecathode - Eanode = 0.99V - (-0.23V), resulting in E°cell = 1.22V.
Next, Q = [Ni2+]/([VO2+]×[H+]²), substituting the given concentrations, Q = (2.5)/(0.083×1.1²).
After calculating Q, we substitute all known values into the Nernst Equation and solve for Ecell. Hence, the cell potential under these nonstandard conditions can be calculated.
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